RELATIONSHIP BETWEEN THE STRUCTURE PARAMETERS OF A SOLID BODY AND THE KINETICS OF DONOR–ACCEPTOR INTERACTION IN HETEROGENEOUS SYSTEMS

Interaction of an organic ligand molecule with the surface of a d-metal or of disperse particles of chemical compounds containing covalent bonds in a nonaqueous solvent (direct synthesis of complex compounds) is determined by the structure parameters of the solid body. The relationships of the rate and energy of activation of the donor–acceptor interaction of the metal with the Grüneisen coeffi cient and the Debye temperature of the metal have been established.
   
Author:  V. Ya. Khentov and Kh. Kh. Khussein
Keywords:  direct synthesis of complex compounds, ligand, nonaqueous solvent, reaction rate, activation energy, structure parameters of a solid body, Grüneisen coeffi cient, Debye temperature of a metal
Page:  754